If if I put a shirt I am planning to tie dye in soda ash for a few hours rather than 10 minutes, does that mean that after I put the colors in it, it wont have to soak for 24 hours, but a shorter period of time?

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No, you'll still need to soak the shirt in the day for the full 24 hours, otherwise the colors won't set properly in the tie dye.

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