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If I want to do refugee work in 3rd world countries, should I join the navy, army, or police force?

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I want to do volunteer work helping 3rd world countries by taking food and building wells and homes etc. I have always thought that joining the police force would give me a better chance at this goal but today a friend suggested the army or the navy. Has anybody here had experience with either of these? Also what option do you think would help me more? Thanks heaps :)