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Diluting alcohol (specifically vodka)

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If I dilute my 1.75 liter bottle of vodka, does the alcohol stay on top? I am trying to get my husband to cut down for health reasons - but he is sneaking my vodka - so I figure if I dilute it, he won't get as much alcohol. I want to know since there is only one bottle, if I should shake it up when I pour mine? He mixes his with cola, so he should not be able to tell the difference. He would know if there were 2 bottles open. Tried that.