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Love and relationships
Health is another one that doesnt show up in some circumstances (I never figured this one out)
As Ty said, Love and Relationships (it seems to be the popular topic) and SOMETIMES health, it will work but just not all the time which is strange.
Only love & relationships isn't in the "all questions" page...health is there, however. If you see an exception to that, please let me know & I'll file a bug 
Answer this Question: "Questions vs Categories"
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Questions vs categories
So I usually just click on the Questions link at the top of the page and then scroll through ALL the Questions. Am I missing Questions? Are there some Categories of Questions that aren't accessed by clicking on the Question link?
If so, which Categories do you have to click on to view "missing" Questions?