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It doesn't reflect (bounce off); it refracts (bends). You can see rainbows only when the sun is shining behind you and it is raining in front of you. Rainbows form when sunlight shines through millions of raindrops. Sunlight is a mixture of colours. When it passes through a raindrop, it is refracted (bent) and the light splits and spreads into seven colours.
Since children sometimes learn concepts like this by doing, here is a link to an experiment to make a rainbow. Have fun!
http://www.first-school.ws/activities/science/rainbow-experiment.htm
Rainbows are made when sunlight and water meet. have you kid play in the sprinklers on a sunny day and give them a special treat when they find the rainbow. I tried that with my krissie when she was three. She LOVED it!
lol
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How do I explain how a rainbow is created in a way that a toddler will understand the explanation?