Yeah, hot air rises to a degree, at the same pressure it's a fraction less dense and is displaced upwards by colder heavier air being falling down into it's place.
It's still cold at high altitudes because as you go higher the pressure drops a lot and the atmosphere mostly gets it's heat from solid ground that's been heated by the sun.
The pressure drops because there's less air above pushing down, even though it's just air really does add up (if you've ever tried to create a vacuum with a plunger or something you're basically pushing against the pressure from all the air in the atmosphere above you, and it's pretty hard work).
Colder air under less pressure is still less dense than hor air under lots of pressure so the hot air won't rise above it.
The less dense air on top radiates heat constantly into space but only gets a trickle of heat conducting up from the ground so it stays pretty cold up there.
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Does heat really rise?




Does heat really rise?
If heat rises why is there always snow on the top of mountins and it gets colder the higher you go?