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I would have to say 100% grape- since that is what red wine is made of- the alcohol comes along because the grape is fermented.
you can have something fermented in nature and it is still what it started out as- the alcohol would simply be a by product.
now if they boiled the alcohol off of it, and condensed it, then it would no longer be considered a grape- just simply alcohol.
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What percentage of red wine is grape?
 



What percentage of red wine is grape?
(approx)