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You need an extra place to store the water.
Fill the 3 liter jug, empty into the five liter container. Then fill it again, and empty 2 of the 3 liters into the five liter container, leaving 1 liter in the 3 liter jug.
Then, empty the five liter container. Fill in the 1 liter from the 3 liter jug into the five, and then fill the 3 liter completely & empty into the five liter container.
4 liters, need to fill the 3 liter jug completely 3 times in total, which wastes five liters of water. With water conservation a very important issue for many communities in the world...I'd buy another jug 
This was in a Die Hard movie, I think it was the second one.

Can you do this puzzle?
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you have a 3 litre jug and a 5 litre jug.and unlimited water.you have to make 4 litre of water in 5 litre jug.try it.